This book covers all aspects of bioavailability, as related to
environmental contaminants. After a discussion of the definition of
bioavailability and its context, focus is placed on the role of risk
assessment and bioavailability. Methods of analysis are then discussed
including a range of atomic spectroscopic and electrochemical techniques
for metal analysis and chromatographic approaches for persistent organic
pollutants (POPs). The occurrence, properties and eco-toxicity of POPs
and metals in the soil/sediment environment are discussed. Particular
emphasis is placed on the uptake of POPs and metals by plants
(phytoextraction). Examples of POPs and metals in the environment are
reviewed.
Methods to assess the bioavailability of POPs and metals in the
environment are discussed. The particular approaches considered are:
- non-exhaustive extraction techniques
- single extraction techniques
- sequential extraction techniques
- use of cyclodextrin and surfactants
- in-vitro gastrointestinal methods including physiological-based
extraction test
- the use of bioasssays including earthworms.
Finally, selected case studies highlight the importance of determining
the bioavailability of POPs and metals.